The Oscar winning humanitarian activist took part in the shoot in 1991 for famed photographer Sean McCall.
In some of the photos, Jolie hair is pulled up into a messy bun with a little bit of make-up.
She uses her hands in a number of poses, across her chest and placed seductively on her thighs.
Despite her troubled years as a teen, Jolie turned out pretty well. Married to one of Hollywood’s producer and actor, Brad Pitt, one can’t help but envy her almost perfect life.
Scroll down to see more photos of the fresh faced diva: